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Kinetic and stoichiometry of the reaction of chlorogenic acid and its alkyl esters against the DPPH radical

Lopez Giraldo Luis Javier, Laguerre Mickaël, Lecomte Jérôme, Figueroa-Espinoza Maria-Cruz, Baréa Bruno, Weiss Jochen, Decker Eric Andrew, Villeneuve Pierre. 2009. Kinetic and stoichiometry of the reaction of chlorogenic acid and its alkyl esters against the DPPH radical. Journal of Agricultural and Food Chemistry, 57 (2) : pp. 863-870.

Journal article ; Article de revue à facteur d'impact
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Quartile : Outlier, Sujet : AGRICULTURE, MULTIDISCIPLINARY / Quartile : Q1, Sujet : FOOD SCIENCE & TECHNOLOGY / Quartile : Q1, Sujet : CHEMISTRY, APPLIED

Abstract : The lipophilization of polar antioxidants such as phenolics is an efficient way to enhance their solubility in apolar media. Thus, in emulsified systems, lipophilized antioxidants are supposed to locate at the lipid/aqueous phase interface and to lead to a better protection of unsaturated lipids. Herein, the antiradical activity of chlorogenic acid (5-CQA) and its corresponding esters with seven fatty alcohols (from methanol to eicosanol) have been achieved using the well-known 2,2-diphenyl-1-picrylhydrazyl (DPPH) method. Hydrophobation was shown to significantly improve the antiradical activity of 5-CQA esters which reached a maximum for butyl- and octyl-chlorogenate. In addition, for both 5-CQA and its esters, it was demonstrated that the global mechanism of DPPHo stabilization proceeded likely by electron transfer (ET), while it appeared that the pathways of DPPHo stabilization were different between 5-CQA and its esters, as confirmed by the LC-MS characterization of reaction products. Finally, strong differences were found between the tested molecules allowing the proposal of different DPPHo stabilization pathways by electron transfer for 5-CQA and its esters. (Résumé d'auteur)

Mots-clés Agrovoc : Candida, Acide chlorogénique, Radical libre, Composé phénolique, Antioxydant

Mots-clés complémentaires : Lipophilisation, Candida antarctica

Classification Agris : Q02 - Food processing and preservation
000 - Autres thèmes

Champ stratégique Cirad : Axe 3 (2005-2013) - Alimentation accessible et de qualité

Auteurs et affiliations

  • Lopez Giraldo Luis Javier, CIRAD-PERSYST-UMR IATE (FRA)
  • Laguerre Mickaël, CIRAD-PERSYST-UMR IATE (FRA)
  • Lecomte Jérôme, CIRAD-PERSYST-UMR IATE (FRA)
  • Figueroa-Espinoza Maria-Cruz, CIRAD-PERSYST-UMR IATE (FRA)
  • Baréa Bruno, CIRAD-PERSYST-UMR IATE (FRA)
  • Weiss Jochen, University of Hohenheim (DEU)
  • Decker Eric Andrew, University of Massachusetts (USA)
  • Villeneuve Pierre, CIRAD-PERSYST-UMR IATE (FRA) ORCID: 0000-0003-1685-1494

Autres liens de la publication

Source : Cirad - Agritrop (https://agritrop.cirad.fr/547846/)

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