Eco-sustainable biorefinery to the management of winery waste by integrating sequential ready-to-use pigments and bioenergy through advanced multi-step kinetic slow pyrolysis

Mussagy Cassamo U., De Souza Mesquita Leonardo M., Rostagno Mauricio A., Haddad Felipe F., Dos Santos Jean L., Scarim Cauê B., Herculano Rondinelli D., Valette Jérémy, Sangare Diakaridia. 2024. Eco-sustainable biorefinery to the management of winery waste by integrating sequential ready-to-use pigments and bioenergy through advanced multi-step kinetic slow pyrolysis. Industrial Crops and Products, 221:119380, 12 p.

Résumé : This study aimed to design a sequential biorefinery from wine-making by-products for the obtaining value-added products, focusing on extracting natural pigments and the evaluation of bioenergy produced by remaining biomass from Carm´en`ere Grape Residues (CGR) through slow pyrolysis. To achieve these goals, solid-liquid extraction of pigments from CGR was performed using a reusable bio-based solvent. Concurrently, these pig- ments' antioxidant activity and toxicity were evaluated in embryo cells, exploring their potential applications in the cosmetic industry. Secondly, it focused on applying the residual colorless biomass derived from the initial extraction process. This involved the evaluation of kinetic triplet : apparent activation energy, pre-exponential factor, and reaction model. From these parameters, the thermodynamic properties (ΔH, ΔG, and ΔS) were estimated. The results from the first step revealed the recovery of 18.21 mg/gCGR of total anthocyanin that exhibited robust antioxidant capabilities and compatibility with biological systems, indicating potential appli- cations in the cosmetic industry. The pyrolysis of residual colorless biomass revealed a complex chemical structure with multiple stages of decomposition. The kinetic parameters, including activation energy and pre- exponential factor, indicated better energy yield than other biomass, highlighting the potential for bioenergy production. The difference between activation energy and standard enthalpy of the reaction was less than 5.72 kJ/mol, indicating a favorable exothermic reaction and the feasibility of the energetic process. This study provides insights into the dual benefits of utilizing CGR for pigments recovering and bioenergy, contributing to sustainable practices towards a circular economy model.

Mots-clés Agrovoc : bioénergie, pyrolyse, antioxydant, propriété physicochimique, indicateur biologique, biomasse, sous-produit

Mots-clés libres : Biorefinery, Grape, Carménère, Residues, Pyrolysis

Agences de financement hors UE : Fundação de Amparo à Pesquisa do Estado de São Paulo, Conselho Nacional de Desenvolvimento Científico e Tecnológico

Auteurs et affiliations

• Mussagy Cassamo U., Pontificia Universidad Catolica de Chile (CHL) - auteur correspondant
• De Souza Mesquita Leonardo M., UNICAMP (BRA)
• Rostagno Mauricio A., UNICAMP (BRA)
• Haddad Felipe F., UNESP (BRA)
• Dos Santos Jean L., UNESP (BRA)
• Scarim Cauê B., UNESP (BRA)
• Herculano Rondinelli D., TIBI (USA)
• Valette Jérémy, CIRAD-PERSYST-UPR BioWooEB (FRA) ORCID: 0009-0000-3371-6417
• Sangare Diakaridia, CIRAD-PERSYST-UPR BioWooEB (FRA) ORCID: 0000-0002-6643-5512

Source : Cirad-Agritrop (https://agritrop.cirad.fr/611036/)

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