Autothermal and allothermal pyrolysis in a continuous fixed bed reactor

Milhe Mathieu, Van de Steene Laurent, Haube Michaël, Commandre Jean-Michel, Fassinou Wanignon Ferdinand, Flamant Gilles. 2013. Autothermal and allothermal pyrolysis in a continuous fixed bed reactor. Journal of Analytical and Applied Pyrolysis, 103 : 102-111.

Quartile : Q1, Sujet : CHEMISTRY, ANALYTICAL / Quartile : Q1, Sujet : SPECTROSCOPY

Résumé : Pyrolysis plays a major role in the optimization of process efficiency and gas quality in two-stage gasifiers. We developed an original reactor at pilot scale to investigate continuous fixed bed pyrolysis, in either allothermal or autothermal operating mode using air injection. Instrumentation and analysis enabled thermal profiles to be established inside the bed along with fine measurement of yields, char composition, permanent gases, and compounds at the outlet of the pyrolysis reactor. Under oxidative conditions, fixed-bed pyrolysis led to smoldering and the stabilization of an ignition front between 10 and 20 cm below the bed surface. With oxidative pyrolysis, yields of organic condensates were lower than with allothermal pyrolysis, whereas the production of pyrolysis water and permanent gases increased considerably. The main conclusion is that during autothermal pyrolysis in fixed-bed conditions, the presence of oxygen promotes oxidation of volatile matter and cracking reactions, thereby increasing the production of pyrolysis water and permanent gases. We observed a significant increase in yields of CO2 and CO, while the yield of char remained comparable to that in allothermal experiments.

Mots-clés Agrovoc : pyrolyse, biomasse, charbon de bois, traitement thermique, rendement, oxydation, gazéification, plante ligneuse, production énergétique, Pinus pinaster, bioénergie

Classification Agris : K50 - Technologie des produits forestiers
P06 - Sources d'énergie renouvelable

Champ stratégique Cirad : Axe 2 (2005-2013) - Biomasse énergie et sociétés du sud

Auteurs et affiliations

• Milhe Mathieu, CIRAD-PERSYST-UPR Biomasse-énergie (FRA)
• Van de Steene Laurent, CIRAD-PERSYST-UPR Biomasse-énergie (FRA) ORCID: 0000-0003-4737-3667
• Haube Michaël, Xylowatt (BEL)
• Commandre Jean-Michel, CIRAD-PERSYST-UPR Biomasse-énergie (FRA) ORCID: 0000-0001-9094-7879
• Fassinou Wanignon Ferdinand
• Flamant Gilles, CNRS (FRA)

Source : Cirad - Agritrop (https://agritrop.cirad.fr/571048/)

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